What is trans-isomerism in alkenes?

What is trans-isomerism in alkenes?

• A. Occurs when substituents are on the same side of a double bond
• B. Occurs when substituents are on opposite sides of a double bond
• C. Refers to the saturation of double bonds
• D. Involves the rearrangement of double bonds

Answer: (B)

Trans-isomerism in alkenes is characterized by the positioning of substituents relative to the carbon-carbon double bond. When you have trans-isomers, the substituents are situated on opposite sides of the double bond. This arrangement affects the physical properties of the molecules, such as boiling points and melting points, due to variations in polarity and steric hindrance. In contrast, when substituents are on the same side of the double bond, this configuration is referred to as cis-isomerism. Understanding these differences is important in organic chemistry as the geometry around the double bond can significantly influence the reactivity and interactions of these compounds. The options related to saturation and rearrangement do not pertain to the concept of isomerism in relation to double bonds.

Trans-isomerism in alkenes is characterized by the positioning of substituents relative to the carbon-carbon double bond. When you have trans-isomers, the substituents are situated on opposite sides of the double bond. This arrangement affects the physical properties of the molecules, such as boiling points and melting points, due to variations in polarity and steric hindrance.

In contrast, when substituents are on the same side of the double bond, this configuration is referred to as cis-isomerism. Understanding these differences is important in organic chemistry as the geometry around the double bond can significantly influence the reactivity and interactions of these compounds. The options related to saturation and rearrangement do not pertain to the concept of isomerism in relation to double bonds.